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HRID 62569作成日:2026年10月23日

p-Toluenesulfonic acid → Diheptyl galactarate

https://huagongshe.com/ja/reaction/62569

反応式

関与物質

役割名称HCID仕込み量
反応物p-Toluenesulfonic acidHCID 6101—
反応物Galactaric acidHCID 3037582—
触媒HCID 178477782HCID 178477782—
溶媒HeptanolHCID 8129—
生成物Diheptyl galactarateHCID 131737197—

反応条件

温度150 °C

反応手順

In one specific embodiment of the present disclosure, 20 ml of 1-heptanol, 1 mmol of galactaric acid, 0.05 mmol of methyltrioxorhenium catalyst, and 0.05 mmol of para-toluenesulfonic acid were poured into a 50 cc reactor. The temperature in the reactor was then raised to 150° C. and the reaction was performed for 12 hours, maintaining the reactor temperature at 150° C. to obtain diheptyl galactarate.

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US09447012B2
出典データセットuspto-grants-2016_09
ORD IDord-f5e7bc175fbd42759b8032b4cebdc309
出典メモuspto-grants-2016_09