関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | p-Toluenesulfonic acid | HCID 6101 | — |
| 反応物 | Galactaric acid | HCID 3037582 | — |
| 触媒 | HCID 178477782 | HCID 178477782 | — |
| 溶媒 | Heptanol | HCID 8129 | — |
| 生成物 | Diheptyl galactarate | HCID 131737197 | — |
反応手順
In one specific embodiment of the present disclosure, 20 ml of 1-heptanol, 1 mmol of galactaric acid, 0.05 mmol of methyltrioxorhenium catalyst, and 0.05 mmol of para-toluenesulfonic acid were poured into a 50 cc reactor. The temperature in the reactor was then raised to 150° C. and the reaction was performed for 12 hours, maintaining the reactor temperature at 150° C. to obtain diheptyl galactarate.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US09447012B2 |
|---|
| 出典データセット | uspto-grants-2016_09 |
|---|
| ORD ID | ord-f5e7bc175fbd42759b8032b4cebdc309 |
|---|
| 出典メモ | uspto-grants-2016_09 |
|---|