4-Methoxyphenol → 4-Methoxycyclohexanol (cis,trans)

HRID 633520

反応式

HRID 633520 の反応式
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([OH:9])=[CH:5][CH:4]=1>C(O)(=O)C.[Pt]=O>[CH3:1][O:2][CH:3]1[CH2:8][CH2:7][CH:6]([OH:9])[CH2:5][CH2:4]1

参加物

4

反応物 1

HCID 90154-Methoxyphenol

生成物 1

HCID 1403324-Methoxycyclohexanol (cis,trans)

試薬・触媒・溶媒 2

HCID 82844Platinum oxide (PtO)触媒HCID 176Acetic Acid溶媒

反応条件

温度
50 °C

実験手順

A mixture of 4-methoxyphenol (0.10 g, 0.806 mmol) in acetic acid (10 mL) was added to platinum oxide (0.020 g, 0.088 mmol) in a 50 mL pressure bottle and heated at 50° C. under hydrogen at 30 psi for 1 hour. The solid was removed by filtration, and the filtrate was concentrated to provide the title compound.

後処理

  1. customThe solid was removed by filtration
  2. concentrationthe filtrate was concentrated

出典と根拠

ORDレコード
ord-2dc8bd4942754b03ab5ddc5dbd1b51dd
出典データセット
uspto-grants-2016_04
特許番号
US09321764B2

関連ノート

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