Hydrazine → 4-(2-Phenylpropan-2-yl)thiosemicarbazide

HRID 634221ノート

反応式

HRID 634221 の反応式
[NH2:1][NH2:2].[N:3]([C:6]([C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)([CH3:8])[CH3:7])=[C:4]=[S:5]>CCO>[C:9]1([C:6]([NH:3][C:4]([NH:1][NH2:2])=[S:5])([CH3:8])[CH3:7])[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1

参加物

4

反応物 2

HCID 9321HydrazineHCID 12376018(2-Isothiocyanatopropan-2-yl)benzene

生成物 1

HCID 133883954-(2-Phenylpropan-2-yl)thiosemicarbazide

試薬・触媒・溶媒 1

HCID 702Ethanol溶媒

実験手順

Anhydrous hydrazine (1.161 mL, 37.0 mmol) (Sigma-Aldrich) was added to a stirring solution of (2-isothiocyanatopropan-2-yl)benzene (6.56 g, 37.0 mmol) in EtOH (150 mL). The reaction was stirred at RT for 2 h to give N-(2-phenylpropan-2-yl)hydrazinecarbothioamide. MS (ESI, pos. ion) m/z: 210.2 (M+1). The material was used without purification.

出典と根拠

ORDレコード
ord-dafd415e8bd1486ba2c2f37684491cb3
出典データセット
uspto-grants-2016_04
特許番号
US09321756B2

反応ノート

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