Acetic Anhydride → 2-Acetyl-1,2,4-triazine-3,5(2H,4H)-dione
反応式
[N:1]1[NH:2][C:3](=[O:8])[NH:4][C:5](=[O:7])[CH:6]=1.[C:9](OC(=O)C)(=[O:11])[CH3:10]>>[C:9]([N:2]1[C:3](=[O:8])[NH:4][C:5](=[O:7])[CH:6]=[N:1]1)(=[O:11])[CH3:10]参加物
3
実験手順
2H-[1,2,4]Triazin-3,5-dione (100 g, 884 mmol) is placed in 600 ml of acetic anhydride at reflux for 1.5 h. The reaction mixture is subsequently concentrated to dryness and the solid obtained is triturated in toluene. After filtering and rinsing with toluene, 130.5 g of beige crystals are isolated.
後処理
- temperatureat reflux for 1.5 h
- concentrationThe reaction mixture is subsequently concentrated to dryness
- customthe solid obtained
- customis triturated in toluene
- filtrationAfter filtering
- washrinsing with toluene, 130.5 g of beige crystals
- customare isolated
出典と根拠
- ORDレコード
- ord-a31f88d4691e424dbd6d44686bd27d99
- 出典データセット
- uspto-grants-2001_02
- 特許番号
- US06191130B1
反応ノート
読み込み中…