Dinitrofluorobenzene → HCID 4922992、化合物

HRID 636335ノート

反応式

HRID 636335 の反応式
[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1F)([O-:3])=[O:2].CN1CCCC1=O.[CH2:21]([NH:24][CH2:25][CH:26]=[CH2:27])[CH:22]=[CH2:23].C(=O)([O-])[O-].[K+].[K+]>O>[CH2:21]([N:24]([CH2:25][CH:26]=[CH2:27])[C:5]1[CH:6]=[CH:7][C:8]([N+:10]([O-:12])=[O:11])=[CH:9][C:4]=1[N+:1]([O-:3])=[O:2])[CH:22]=[CH2:23]

参加物

6

反応物 4

HCID 6264DinitrofluorobenzeneHCID 11430Potassium CarbonateHCID 13387N-methyl-2-pyrrolidoneHCID 31279Diallylamine

生成物 1

HCID 4922992HCID 4922992、化合物収率 111%

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

A mixture of 2,4-dinitrofluorobenzene (9.3 g), N-methylpyrrolidinone (NMP, 50 mL), diallylamine (5.82 g) and potassium carbonate (6.9 g) was stirred at ambient temperature for 1 h. The mixture was poured into water and extracted with ethyl ether. The extract was washed twice with water, once with saturated brine solution, and dried over magnesium sulfate. Concentration of the extract gave N,N-diallyl-2,4-dinitrobenzenamine as a yellow oil (14.6 g).

後処理

  1. extractionextracted with ethyl ether
  2. washThe extract was washed twice with water, once with saturated brine solution
  3. dry with materialdried over magnesium sulfate

出典と根拠

ORDレコード
ord-a5ae0ba73d5644adaefa853ea14ad085
出典データセット
uspto-grants-2001_02
特許番号
US06194039B1

反応ノート

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