Ethanol → HCID 22611021、化合物
反応式
[N+:1]([C:4]1[CH:22]=[CH:21][CH:20]=[CH:19][C:5]=1[NH:6][C:7]1[CH:12]=[CH:11][C:10]([NH:13][C:14]2[S:15][CH:16]=[CH:17][N:18]=2)=[CH:9][CH:8]=1)([O-])=O.O.O.O.O.O.O.O.O.O.[S-2].[Na+].[Na+].[Cl-].[NH4+].C(O)C>O>[NH2:1][C:4]1[CH:22]=[CH:21][CH:20]=[CH:19][C:5]=1[NH:6][C:7]1[CH:12]=[CH:11][C:10]([NH:13][C:14]2[S:15][CH:16]=[CH:17][N:18]=2)=[CH:9][CH:8]=1参加物
6
実験手順
A mixture of 2-nitro-N-(4-(2-thiazolylamino)phenyl)aniline (1.2 g, 3.8 mmol), sodium sulfide nona hydrate (4.61, 19.2 mmol), ammonium chloride (1.03 g, 19.2 mmol) and ethanol (40 ml) was stirred at reflux for 40 h. Water (50 ml) was added, the mixture was stirred an d filtered. Yield 0.49 g, 46%. M.p. 184-186° C.
後処理
- temperatureat reflux for 40 h
- stirringthe mixture was stirred an d
- filtrationfiltered
出典と根拠
- ORDレコード
- ord-02188d11568d4ab08211d4463fe34ac1
- 出典データセット
- uspto-grants-2001_02
- 特許番号
- US06194447B1
反応ノート
読み込み中…