関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 3-(Chlorocarbonyl)phenyl acetate | HCID 12998558 | — |
| 反応物 | Dimethyl sulphoximine potassium salt | HCID 86740516 | — |
| 溶媒 | Tetrahydrofuran | HCID 8028 | — |
| 生成物 | N-(m-Acetoxybenzoyl)-S,S-dimethyl-sulphoximine | HCID 20256530 | — |
反応手順
A solution of 99.3 g of m-acetoxybenzoyl chloride in 150 ml of absolute tetrahydrofuran is added dropwise at -35° C. during 20 minutes while stirring to the dimethyl sulphoximine potassium salt suspension and the mixture is then stirred at -35° C. for 30 minutes. N-(m-Acetoxybenzoyl)-S,S-dimethyl-sulphoximine is thus formed in suspension.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04556413 |
|---|
| 出典データセット | uspto-grants-1985_12 |
|---|
| ORD ID | ord-7abe3c7ad9e0455ab3840a266774c0b4 |
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| 出典メモ | uspto-grants-1985_12 |
|---|
