1-Bromoheptadecane → 1-O-Heptadecyl-2-O-methyl-rac-glycerol

反応式

[CH3:1][O:2][CH:3]([CH2:6][OH:7])[CH2:4][OH:5].Br[CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25]>>[CH2:25]([O:5][CH2:4][CH:3]([O:2][CH3:1])[CH2:6][OH:7])[CH2:24][CH2:23][CH2:22][CH2:21][CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH3:9]

参加物

反応物 2

HCID 190221-Bromoheptadecane

HCID 111709312-Methoxypropane-1,3-diol

生成物 1

HCID 202525081-O-Heptadecyl-2-O-methyl-rac-glycerol収率 45%

実験手順

2-Methylglycerol (10.6 g) and 10.7 g of 1-bromoheptadecane were reacted and worked up in accordance with Example 5-(i) to give 5.2 g of the above-identified alcohol compound.

出典と根拠

ORDレコード: ord-ed79c45fbcd64bb9b99faa7bc52f8460
出典データセット: uspto-grants-1985_12
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04562005

反応ノート

読み込み中…