化工社化工社 化学情報印刷レポート · 研究参考用
Ethylene carbonate → 18-Crown-6
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Ethylene carbonate | HCID 7303 | — |
| 反応物 | 2-Decanone | HCID 12741 | — |
| 反応物 | Cesium Chloride | HCID 24293 | — |
| 反応物 | 15-Crown-5 | HCID 36336 | — |
| 生成物 | 18-Crown-6 | HCID 28557 | — |
反応手順
According to this invention, 22 grams of ethylene carbonate, 11 grams of 2-decanone and 0.565 grams of CsCl were placed in a 100 ml round-bottomed flask which was fitted with a thermometer, distillation head and a cold trap. The flask was heated in an oil bath (with magnetic stirring) at about 150° C. to about 175° C. for about 8 hours. Analysis of the reaction mixture by gas chromatography showed that 15-Crown-5 and 18-Crown-6 were formed.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04562272 |
| 出典データセット | uspto-grants-1985_12 |
| ORD ID | ord-71939a7f614441ec9cb4a5dd17fd5afb |
| 出典メモ | uspto-grants-1985_12 |