化工社化工社 化学情報印刷レポート · 研究参考用
[1,3]Oxathiolo[5,4-c]pyridin-6-ylmethanol → [1,3]Oxathiolo[5,4-c]pyridine-6-carbaldehyde
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | [1,3]Oxathiolo[5,4-c]pyridin-6-ylmethanol | HCID 67426109 | — |
| 触媒 | HCID 178418406 | HCID 178418406 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | [1,3]Oxathiolo[5,4-c]pyridine-6-carbaldehyde | HCID 59254367 | 62.3% |
反応手順
[1,3]oxathiolo[5,4-c]pyridine-6-methanol (0.92 g, 5.44 mmole) was treated with manganese (IV) oxide (3.83 g, 44 mmole) at RT in DCM (50 mL) to afford the aldehyde (567 mg, 62%) as a solid; MS (+ve ion electrospray) m/z 168 (MH+).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07691850B2 |
| 出典データセット | uspto-grants-2010_04 |
| ORD ID | ord-e811c26613054254a23fc21a8c0d7428 |
| 出典メモ | uspto-grants-2010_04 |