Sodium dithiobenzoate → Bis(thiobenzoyl) Disulfide

HRID 640033

反応式

HRID 640033 の反応式
[C:1]([S-:9])(=[S:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[Na+]>O.[Fe-3](C#N)(C#N)(C#N)(C#N)(C#N)C#N.[K+].[K+].[K+]>[C:1]([S:9][S:9][C:1](=[S:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1)(=[S:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

参加物

4

反応物 1

HCID 11030352Sodium dithiobenzoate2 回

生成物 1

HCID 10902862Bis(thiobenzoyl) Disulfide

試薬・触媒・溶媒 2

HCID 178511488HCID 178511488、化合物触媒2 回HCID 962Water溶媒

実験手順

Potassium ferricyanide (III) (32.93 g) was dissolved in deionized water (500.0 mL). Sodium dithiobenzoate solution (350.0 mL) was transferred to a 1 L conical flask equipped with a magnetic stir bar. Potassium ferricyanide solution was added drop wise to the sodium dithiobenzoate via an addition funnel over a period of one hour under vigorous stirring. The red precipitate was filtered and washed with deionized water until the washings become colorless. The solid was dried in vacuum at room temperature overnight; the product was recrystallized from ethanol.

後処理

  1. customequipped with a magnetic stir bar
  2. filtrationThe red precipitate was filtered
  3. washwashed with deionized water until the washings
  4. customThe solid was dried in vacuum at room temperature overnight
  5. customthe product was recrystallized from ethanol

出典と根拠

ORDレコード
ord-061b854e51fb4b27ae210ae02eac35d1
出典データセット
uspto-grants-2010_04
特許番号
US07691937B2

関連ノート

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