Triethylamine → p-Ethoxalyloxyethylstyrene

HRID 6407

反応式

HRID 6407 の反応式
[OH:1][CH2:2][CH2:3][C:4]1[CH:11]=[CH:10][C:7]([CH:8]=[CH2:9])=[CH:6][CH:5]=1.C(N(CC)CC)C.[C:19](Cl)([C:21]([O:23][CH2:24][CH3:25])=[O:22])=[O:20]>C1C=CC=CC=1>[C:19]([O:1][CH2:2][CH2:3][C:4]1[CH:11]=[CH:10][C:7]([CH:8]=[CH2:9])=[CH:6][CH:5]=1)([C:21]([O:23][CH2:24][CH3:25])=[O:22])=[O:20]

参加物

5

反応物 3

HCID 8471TriethylamineHCID 20884Ethoxalyl chlorideHCID 220518322-(4-Vinylphenyl)ethanol

生成物 1

HCID 67847970p-Ethoxalyloxyethylstyrene

試薬・触媒・溶媒 1

HCID 241Benzene溶媒

反応条件

温度
10 °C

実験手順

A 200 ml flask equipped with a stirrer, a thermometer and a dropping funnel was charged with 14.8 g (0.1 mol) of p-hydroxyethylstyrene, 150 ml of benzene and 10.1 g (0.1 mol) of triethylamine and cooled to 10° C. To the mixture was added dropwise with stirring 13.7 g (0.1 mol) of ethoxalyl chloride for one hour at 10° C. to precipitate a hydrochloride of triethylamine (white solid). After mixting at room temperature for 2 hours, 80 g of hexane was added to complete precipitation of the hydrochloride. The hydrochloride is removed by filteration and the resultant filtrate was condensed to obtain the aimed compound. The compound was identified by 1H NMR (360 Mz) and IR. ##STR7##

後処理

  1. customA 200 ml flask equipped with a stirrer
  2. additionTo the mixture was added dropwise
  3. customto precipitate a hydrochloride of triethylamine (white solid)
  4. addition80 g of hexane was added to complete precipitation of the hydrochloride
  5. customThe hydrochloride is removed by filteration
  6. customcondensed

出典と根拠

ORDレコード
ord-eb42087260a94c678501a68bb3d83b03
出典データセット
uspto-grants-1993_09
特許番号
US05248749

関連ノート

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