化工社化工社 化学情報印刷レポート · 研究参考用
2-Cyclopenten-1-one → 6,6-Diethoxybicyclo[3.2.0]heptan-2-one
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 2-Cyclopenten-1-one | HCID 13588 | — |
| 反応物 | 1,1-Diethoxyethene | HCID 137673 | — |
| 溶媒 | Pentane | HCID 8003 | — |
| 生成物 | 6,6-Diethoxybicyclo[3.2.0]heptan-2-one | HCID 12564365 | — |
反応手順
To a solution of cyclopent-2-enone (3.7 g, 45 mmol) in pentane (80 mL) was added 1,1-diethoxyethene (89 mL, 677 mmol). The mixture was put in an ACE Photo Reactor (450 W lamp), and stirred at RT for 20 hr. It was concentrated to give the title compound as a pale yellow oil.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07696241B2 |
| 出典データセット | uspto-grants-2010_04 |
| ORD ID | ord-cb3b74a5e9a4424bb222409ea0cf03ea |
| 出典メモ | uspto-grants-2010_04 |