3-Mercaptophenylboronic Acid → 3-(4-Carboxymethyl-benzylsulfanyl)phenylboronic acid

反応式

[SH:1][C:2]1[CH:3]=[C:4]([B:8]([OH:10])[OH:9])[CH:5]=[CH:6][CH:7]=1.Br[CH2:12][C:13]1[CH:18]=[CH:17][C:16]([CH2:19][C:20]([OH:22])=[O:21])=[CH:15][CH:14]=1>>[C:20]([CH2:19][C:16]1[CH:17]=[CH:18][C:13]([CH2:12][S:1][C:2]2[CH:3]=[C:4]([B:8]([OH:10])[OH:9])[CH:5]=[CH:6][CH:7]=2)=[CH:14][CH:15]=1)([OH:22])=[O:21]

参加物

反応物 2

HCID 27739223-Mercaptophenylboronic Acid

HCID 45190564-(Bromomethyl)phenylacetic acid

生成物 1

HCID 669137793-(4-Carboxymethyl-benzylsulfanyl)phenylboronic acid

実験手順

3-(4-Carboxymethyl-benzylsulfanyl)-phenylboronic acid was prepared from 3-mercaptophenylboronic acid and 4-bromomethylphenyl acetic acid according to the procedure of Example 12;

出典と根拠

ORDレコード: ord-4f0008132cf04331b00a52f8f46ce1a4
出典データセット: uspto-grants-2010_04
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07700595B2

反応ノート

読み込み中…