1-[3-(tert-Butyldimethylsilanyloxy)phenyl]propan-1-ol → 1-[3-(tert-Butyldimethylsilanyloxy)phenyl]propan-1-one

HRID 644569ノート

反応式

HRID 644569 の反応式
[Si:1]([O:8][C:9]1[CH:10]=[C:11]([CH:15]([OH:18])[CH2:16][CH3:17])[CH:12]=[CH:13][CH:14]=1)([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:3])[CH3:2]>[O-2].[O-2].[Mn+4]>[Si:1]([O:8][C:9]1[CH:10]=[C:11]([C:15](=[O:18])[CH2:16][CH3:17])[CH:12]=[CH:13][CH:14]=1)([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:3])[CH3:2]

参加物

3

反応物 1

HCID 685795511-[3-(tert-Butyldimethylsilanyloxy)phenyl]propan-1-ol

生成物 1

HCID 150499531-[3-(tert-Butyldimethylsilanyloxy)phenyl]propan-1-one

試薬・触媒・溶媒 1

HCID 178418406HCID 178418406、化合物触媒

実験手順

In a manner analogous to example 1j, by reaction of 45 g (0.17 mol) of 1-[3-(tert-butyldimethylsilanyloxy)phenyl]propan-1-ol with (148 g, 1.7 mol) of manganese dioxide. A yellow oil is obtained (m=45 g, Y=100%).

後処理

  1. customA yellow oil is obtained (m=45 g, Y=100%)

出典と根拠

ORDレコード
ord-51472ba040744b56ad5abf194f59e5cb
出典データセット
uspto-grants-2010_04
特許番号
US07700657B2

反応ノート

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