1-Aminoanthraquinone → 2-Chloro-4,6-bis-(1-aminoanthraquinonyl)-s-triazine

HRID 64623

反応式

HRID 64623 の反応式
[NH2:1][C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[C:7](=[O:17])[C:6]=2[CH:5]=[CH:4][CH:3]=1.[N:18]1[C:25](Cl)=[N:24][C:22](Cl)=[N:21][C:19]=1[Cl:20]>[N+](C1C=CC=CC=1)([O-])=O>[Cl:20][C:19]1[N:18]=[C:25]([C:3]2[CH:4]=[CH:5][C:6]3[C:7](=[O:17])[C:8]4[C:13](=[CH:12][CH:11]=[CH:10][CH:9]=4)[C:14](=[O:16])[C:15]=3[C:2]=2[NH2:1])[N:24]=[C:22]([C:3]2[CH:4]=[CH:5][C:6]3[C:7](=[O:17])[C:8]4[C:13](=[CH:12][CH:11]=[CH:10][CH:9]=4)[C:14](=[O:16])[C:15]=3[C:2]=2[NH2:1])[N:21]=1

参加物

4

反応物 2

HCID 67101-AminoanthraquinoneHCID 7954Cyanuric chloride

生成物 1

HCID 566208202-Chloro-4,6-bis-(1-aminoanthraquinonyl)-s-triazine

試薬・触媒・溶媒 1

HCID 7416Nitrobenzene溶媒

実験手順

A dispersion of 22.3 parts of 1-aminoanthraquinone in 200 ml of nitrobenzene was brought to 100° C. and additioned with 9.22 parts of cyanuryl chloride and successively brought to 190° C. for 2 hours. The reaction mixture was filtered at a temperature of 150° C. and the cake was washed several times with methanol and then with n-heptane and was dried in an oven at a temperature of 110° C. About 23 parts of 2-chloro-4,6-bis-(1-aminoanthraquinonyl)-s-triazine were obtained.

後処理

  1. customwas brought to 100° C.
  2. filtrationThe reaction mixture was filtered at a temperature of 150° C.
  3. washthe cake was washed several times with methanol
  4. dry with materialwith n-heptane and was dried in an oven at a temperature of 110° C

出典と根拠

ORDレコード
ord-39c995a28b34492e88629f18392b81bc
出典データセット
uspto-grants-1986_09
特許番号
US04609404

関連ノート

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