Acetyl chloride → HCID 54351123、化合物

HRID 647033

反応式

HRID 647033 の反応式
C(Cl)(=[O:3])C.[P:5]([O:14][CH2:15][CH2:16][Cl:17])([O:10][CH2:11][CH2:12][Cl:13])[O:6][CH2:7][CH2:8]Cl>C(Cl)CCl>[P:5]([O:14][CH2:15][CH2:16][Cl:17])([O:10][CH2:11][CH2:12][Cl:13])[O:6][C:7](=[O:3])[CH3:8]

参加物

4

反応物 2

HCID 6367Acetyl chlorideHCID 8783Tris(2-chloroethyl) phosphite

生成物 1

HCID 54351123HCID 54351123、化合物

試薬・触媒・溶媒 1

HCID 111,2-Dichloroethane溶媒

実験手順

The same equipment and procedure as in Example 1 was employed. The reaction flask was charged with 100 ml ethylene dichloride and 85 g acetyl chloride (1.1 mole). The addition of 270 g (1.0 mole) tris (β-chloroethyl) phosphite was commenced dropwise and continued for one hour during which there was a slow exotherm to 35° C. After addition of the triphosphite the reaction continued with a self-maintained exotherm at about 40° C. for three hours and then a slow return to ambient temperature while stirring overnight. The pink acetyl bis(β-chloroethyl) phosphite was isolated by rotary evaporatory at 50° C. and 15 torr. The yield was 261 g; acid number 2; purity by infrared analysis was about 75%.

後処理

  1. customto 35° C
  2. waitcontinued with a self-maintained exotherm at about 40° C. for three hours

出典と根拠

ORDレコード
ord-7f2eae64cf9d43a7a79072298464b4a8
出典データセット
uspto-grants-1983_10
特許番号
US04407765

関連ノート

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