2-Chloroacetophenone → HCID 20485523、化合物
反応式
[CH2:1]([Cl:10])[C:2]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)=[O:3].[O:11]1[CH2:16][CH2:15][N:14]([C:17]2[S:21][S:20][C:19](=[S:22])[CH:18]=2)[CH2:13][CH2:12]1>C(O)C>[Cl-:10].[CH2:1]([S:22][C:19]1[S:20][S:21][C:17](=[N+:14]2[CH2:15][CH2:16][O:11][CH2:12][CH2:13]2)[CH:18]=1)[C:2]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)=[O:3]参加物
4
反応条件
- 温度
- 10 °C
実験手順
Phenacyl chloride (10.5 g) is added to a suspension of 5-morpholino-1,2-dithiol-3-thione (9.85 g) in ethanol (200 cc), and the reaction mixture is kept under reflux for 3 hours. After cooling to a temperature of about 10° C., the insoluble product formed is filtered off and washed with ethanol (30 cc). After drying, N-(5-phenacylthio-1,2-dithiol-3-ylidene)-morpholinium chloride (14.3 g) is obtained, which melts at 138° C. and is solvated by 9% of ethanol.