Sulfuric Acid → HCID 86739048、化合物
反応式
[S:1](=[O:5])(=[O:4])([OH:3])[OH:2].[Cl-].[CH2:7]([S:16][C:17]1[S:21][S:20][C:19](=[N+:22]2[CH2:27][CH2:26][O:25][CH2:24][CH2:23]2)[CH:18]=1)[C:8]([C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)=[O:9]>C(O)C>[S:1]([O-:5])([OH:4])(=[O:3])=[O:2].[CH2:7]([S:16][C:17]1[S:21][S:20][C:19](=[N+:22]2[CH2:27][CH2:26][O:25][CH2:24][CH2:23]2)[CH:18]=1)[C:8]([C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)=[O:9]参加物
4
反応条件
- 温度
- 10 °C
実験手順
A solution of concentrated sulphuric acid (d=1.83; 0.2 cc) in ethanol (5 cc) is added to a solution of N-(5-phenacylthio-1,2-dithiol-3-ylidene)-morpholinium chloride (0.75 g) in ethanol (20 cc) under reflux. After cooling to a temperature of about 10° C., the insoluble product formed is filtered off and washed with ethanol (4 cc). After drying, N-(5-phenacylthio-1,2-dithiol-3-ylidene)-morpholinium hydrogensulphate (0.8 g), melting at 192° C., is obtained.