HCID 178490397、化合物 → BENZYL ALCOHOL, o-(5-(m-METHOXYPHENYL)-s-TRIAZOL-3-YL)-

HRID 647603ノート

反応式

HRID 647603 の反応式
[CH3:1][O:2][C:3]1[CH:4]=[C:5]([CH:19]=[CH:20][CH:21]=1)[CH:6]=[N:7][NH:8][C:9]1[C:14]2[CH:15]=[CH:16][CH:17]=[CH:18][C:13]=2[CH2:12][O:11][N:10]=1>C1(C)C(C)=CC=CC=1>[OH:11][CH2:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][C:14]=1[C:9]1[NH:8][N:7]=[C:6]([C:5]2[CH:19]=[CH:20][CH:21]=[C:3]([O:2][CH3:1])[CH:4]=2)[N:10]=1

参加物

3

反応物 1

HCID 178490397HCID 178490397、化合物

生成物 1

HCID 53228BENZYL ALCOHOL, o-(5-(m-METHOXYPHENYL)-s-TRIAZOL-3-YL)-

試薬・触媒・溶媒 1

HCID 7237O-Xylene溶媒

実験手順

A suspension of 16 g of 4-[2-(3-methoxybenzyliden)hydrazino]-1H-2,3-benzoxazine in 160 cc of anhydrous xylene is refluxed for 45 minutes and then, cooled in an ice bath. The solid which precipitates is recovered by filtration and recrystallized from ethanol yielding 14.7 g of the compound of the title. M.p. 157°-59° C.

後処理

  1. temperatureis refluxed for 45 minutes
  2. temperaturecooled in an ice bath
  3. customThe solid which precipitates
  4. filtrationis recovered by filtration
  5. customrecrystallized from ethanol yielding 14.7 g of the compound of the title

出典と根拠

ORDレコード
ord-7d8462bd23b44b4ab9a60edb9bfd093f
出典データセット
uspto-grants-1983_10
特許番号
US04409388

反応ノート

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