Oleic Acid → Oleyl Alcohol

HRID 647756

反応式

HRID 647756 の反応式
[C:1]([OH:20])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[H][H]>>[C:1]([O:20][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[CH2:1]([OH:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]

参加物

4

反応物 2

HCID 445639Oleic AcidHCID 178418361HCID 178418361、化合物

生成物 2

HCID 5284499Oleyl AlcoholHCID 5364672Oleyl Oleate

実験手順

As in the preceeding examples, 200 grams of oleic acid and 10 grams of the catalyst system prepared according to the above paragraph were treated in a manner similar to that set forth in Example I above, that is, by reaction at a temperature of 300° C. and a pressure of 1000 psi of hydrogen for a period of 4 hours. After the 4 hour reaction period had elapsed, heating was discontinued, the autoclave was allowed to return to room temperature, and the excess pressure was vented. Analysis of the reaction product after separation from the catalyst disclosed that there had been a 94% reduction of the carboxyl moieties to form oleyl oleate, oleyl alcohol as well as geometric and positional isomers thereof with an 83% reduction of the double bond.

後処理

  1. additionwere treated in a manner similar to that set forth in Example I above
  2. customthat is, by reaction at a temperature of 300° C.
  3. customAfter the 4 hour reaction period
  4. temperatureheating
  5. customto return to room temperature
  6. customAnalysis of the reaction product after separation from the catalyst

出典と根拠

ORDレコード
ord-4ebdeb303e43432b8d95421ed166a0f6
出典データセット
uspto-grants-1983_10
特許番号
US04410460

関連ノート

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