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Pyridine → Methyl N-[[[[[(diethoxyphosphinothioyl)ethylamino]sulfinyl]methylamino]carbonyl]oxy]ethanimidothioate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Pyridine | HCID 1049 | — |
| 反応物 | Methomyl | HCID 4109 | — |
| 反応物 | Thionyl Chloride | HCID 24386 | — |
| 反応物 | O,O-Diethyl N-ethylphosphoramidothioate | HCID 352352 | — |
| 生成物 | Methyl N-[[[[[(diethoxyphosphinothioyl)ethylamino]sulfinyl]methylamino]carbonyl]oxy]ethanimidothioate | HCID 86739073 | — |
反応手順
Methyl N-[[[[[(diethoxyphosphinothioyl)ethylamino]sulfinyl]methylamino]carbonyl]oxy]ethanimidothioate was prepared by the procedure employed in Example 9, by reacting methyl N-[[(methylamino)carbonyl]oxy]ethanimidothioate (2.43 g, 0.015 mole), thionyl chloride (1.79 g, 0.015 mole), and O,O-diethyl ethylphosphoramidothioate (2.96 g, 0.015 mole) in pyridine (10 ml). Recrystallization from chloroform-hexane afforded 2.95 g of colorless prisms of the formula below, mp 67~68°. ##STR25##
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04410518 |
| 出典データセット | uspto-grants-1983_10 |
| ORD ID | ord-3e866b333c244192bacb55b5ff56d21b |
| 出典メモ | uspto-grants-1983_10 |