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Thionyl Chloride → Methyl 2-(dimethylamino)-N-[[[[[(diethoxyphosphinothioyl)cyclopentylamino]sulfinyl]methylamino]carbonyl]oxy]-2-oxoethanimidothioate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Thionyl Chloride | HCID 24386 | — |
| 反応物 | Oxamyl | HCID 31657 | — |
| 反応物 | O,O-diethyl cyclopentylphosphoramidothioate | HCID 20483188 | — |
| 溶媒 | Pyridine | HCID 1049 | — |
| 生成物 | Methyl 2-(dimethylamino)-N-[[[[[(diethoxyphosphinothioyl)cyclopentylamino]sulfinyl]methylamino]carbonyl]oxy]-2-oxoethanimidothioate | HCID 86739082 | — |
反応手順
Methyl 2-(dimethylamino)-N-[[[[[(diethoxyphosphinothioyl)cyclopentylamino]sulfinyl]methylamino]carbonyl]oxy]-2-oxoethanimidothioate was prepared by the procedure employed in Example 21, by reacting methyl 2-(dimethylamino)-N-[[(methylamino)carbonyl]oxy]-2-oxoethanimidothioate (3.29 g, 0.015 mole), thionyl chloride (1.79 g, 0.015 mole), and O,O-diethyl cyclopentylphosphoramidothioate (3.56 g, 0.015 mole) in pyridine (10 ml). Column chromatography afforded 2.5 g of an oil of the formula below, nD24 : 1.5322. ##STR43##
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04410518 |
| 出典データセット | uspto-grants-1983_10 |
| ORD ID | ord-9f0e32e3b13a4b779361d15305154456 |
| 出典メモ | uspto-grants-1983_10 |