Water → Pyrinuron

HRID 648071

反応式

HRID 648071 の反応式
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([NH:10][C:11](=[O:14])OC)=[CH:6][CH:5]=1)([O-:3])=[O:2].[NH2:15][CH2:16][C:17]1[CH:18]=[N:19][CH:20]=[CH:21][CH:22]=1.O>C1(C)C=CC=CC=1.CO>[N+:1]([C:4]1[CH:5]=[CH:6][C:7]([NH:10][C:11]([NH:15][CH2:16][C:17]2[CH:18]=[N:19][CH:20]=[CH:21][CH:22]=2)=[O:14])=[CH:8][CH:9]=1)([O-:3])=[O:2]

参加物

6

反応物 3

HCID 962WaterHCID 310183-PyridinemethanamineHCID 74752Carbamic acid, N-(4-nitrophenyl)-, methyl ester

生成物 1

HCID 40813Pyrinuron

試薬・触媒・溶媒 2

HCID 887Methanol溶媒HCID 1140Toluene溶媒2 回

実験手順

11.77 g (0.06 mole) of methyl N-(4-nitrophenyl)carbamate, 5.4 g (0.05 mole) of 3-aminomethyl-pyridine, 18.7 g (0.065 mole) of Genamin SH 302 D (a mixture of N,N-dimethyl-C16-18 alkylamines sold by the firm Hoechst AG) and 200 ml of toluene are introduced into the apparatus described in Example 4, and the mixture is boiled for 4 hours. During this period 15 ml of a mixture of water, methanol and toluene accumulate in the trap. The separated solid is filtered off, washed twice with 10 ml of hot toluene, and the resulting mixture is used as reaction medium in the above reaction. The mother liquor is recycled 10 times. The results of the individual cycles are summarized in Table 1.

後処理

  1. additionare introduced into the apparatus
  2. filtrationThe separated solid is filtered off
  3. washwashed twice with 10 ml of hot toluene
  4. customthe resulting mixture is used as reaction medium in the above reaction
  5. customThe results of the individual cycles

出典と根拠

ORDレコード
ord-fbb6ea9090cb48c89a60c8b368dc1926
出典データセット
uspto-grants-1983_10
特許番号
US04410697

関連ノート

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