化工社化工社 化学情報印刷レポート · 研究参考用
4-(Trifluoromethylthio)nitrobenzene → 4-((Trifluoromethyl)thio)aniline
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 4-(Trifluoromethylthio)nitrobenzene | HCID 4210035 | — |
| 触媒 | Adams' catalyst | HCID 345198 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | 4-((Trifluoromethyl)thio)aniline | HCID 123054 | — |
反応手順
To p-nitrophenyl trifluoromethyl sulfide (3.0 g) in absolute ethanol (30 ml) is added Adams catalyst (Pt2O, 0.026 g). The mixture is hydrogenated in a Parr vessel at 50 lbs/sq. in. for about 15 min. The reaction is worked up by filtering through Celite and evaporating to yield p-aminophenyl trifluoromethyl sulfide.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04411912 |
| 出典データセット | uspto-grants-1983_10 |
| ORD ID | ord-1746313fa2d346c3bcf9719c18b8d492 |
| 出典メモ | uspto-grants-1983_10 |