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Hydrazinecarboxaldehyde, 2-(4-nitrophenyl)- → Hydrazinecarboxaldehyde, 2-(4-aminophenyl)-
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Hydrazinecarboxaldehyde, 2-(4-nitrophenyl)- | HCID 5008489 | — |
| 触媒 | HCID 178418390 | HCID 178418390 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | Hydrazinecarboxaldehyde, 2-(4-aminophenyl)- | HCID 113189 | 81.9% |
反応手順
Then, 30 g of 1-formyl-2-(4-nitrophenyl)hydrazine was catalytically reduced in 1.6 liters of ethanol at room temperature using palladium-carbon as a catalyst. The reaction mixture was filtered to remove the catalyst and the filtrate was evaporated to dryness to provide 20.5 g of 1-formyl-2-(4-aminophenyl)hydrazine having a melting point of 123°-125° C. as a light brown solid.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04737452 |
| 出典データセット | uspto-grants-1988_04 |
| ORD ID | ord-7d946c2d603649f39489bd0293d466a3 |
| 出典メモ | uspto-grants-1988_04 |