Water → HCID 86757237、化合物

HRID 650129ノート

反応式

HRID 650129 の反応式
[Br-:1].[CH2:2]([N+:5]1([CH2:12][CH:13]=[CH2:14])[CH2:11][CH2:10][CH2:9][CH2:8]C[CH2:6]1)[CH:3]=[CH2:4].[Cl-:15].[CH2:16]([NH2+:19][CH2:20][CH:21]=[CH2:22])[CH:17]=[CH2:18].[OH2:23]>Cl.Cl.N(C(C(=N)N)(C)C)=NC(C(=N)N)(C)C>[Br-:1].[CH2:12]([N+:5]1([CH2:2][CH:3]=[CH2:4])[CH2:6][CH2:8][CH:9]([OH:23])[CH2:10][CH2:11]1)[CH:13]=[CH2:14].[Cl-:15].[CH2:16]([NH2+:19][CH2:20][CH:21]=[CH2:22])[CH:17]=[CH2:18]

参加物

5

反応物 3

HCID 962WaterHCID 10898762Diallylamine hydrochlorideHCID 21714422HCID 21714422、化合物

生成物 1

HCID 86757237HCID 86757237、化合物

試薬・触媒・溶媒 1

HCID 763442,2'-Azobis(2-methylpropanimidamide) dihydrochloride触媒

反応条件

温度
70 °C

実験手順

N,N-diallylhomopiperidinium bromide (13.0 g, EXAMPLE 4) and diallylammonium chloride (2.7 g, EXAMPLE 7) were dissolved in 15.0 g deionized water. To this aqueous solution was added 0.5 g of 2,2′-azobis(2-amidinopropane) dihydrochloride, the reaction mixture was bubbled with a slow stream of nitrogen gas for 45 minutes. While stirring, the temperature was raised to 70° C. The reaction mixture was stirred at 70° C. for 48 hours. After cooling to room temperature, 30.0 g of viscous polymer solution was obtained.

後処理

  1. customthe reaction mixture was bubbled with a slow stream of nitrogen gas for 45 minutes
  2. stirringThe reaction mixture was stirred at 70° C. for 48 hours
  3. temperatureAfter cooling to room temperature

出典と根拠

ORDレコード
ord-06da743b5b154aeab0135c3524fbeb69
出典データセット
uspto-grants-2001_08
特許番号
US06271264B1

反応ノート

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