関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Benzoyl chloride | HCID 7412 | — |
| 反応物 | 2-Chloroethyl methylcarbonate | HCID 20235240 | — |
| 触媒 | Tetrabutylphosphonium bromide | HCID 76564 | — |
| 生成物 | 2-Chloroethylbenzoate | HCID 95952 | 59% |
反応手順
A mixture of 6.93 g (0.05 mole) of 2-chloroethyl methyl carbonate, 7.03 g (0.05 mole) of benzoyl chloride and 0.85 g (0.0025 mole) of tetra-n-butylphosphonium bromide was heated to 150° C. After 3 hours, gas evolution had ceased and distillation gave 5.44 g (59 percent yield) of 2-chloroethyl benzoate at b.p. 81° C.-82° C./0.4 mm Hg.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04612386 |
|---|
| 出典データセット | uspto-grants-1986_09 |
|---|
| ORD ID | ord-1e8f3f5467cc4c8d83a5e28268ebfcf8 |
|---|
| 出典メモ | uspto-grants-1986_09 |
|---|
