関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Benzoyl chloride | HCID 7412 | — |
| 反応物 | Carbonic acid, di-2-propen-1-yl ester | HCID 84764 | — |
| 触媒 | Zincchloride | HCID 3007855 | — |
| 生成物 | Allyl benzoate | HCID 11406 | 82% |
反応手順
In a glass reactor benzoyl chloride (7.03 g, 0.05 mole), diallyl carbonate (7.1 g, 0.05 mole) and zinc chloride (0.136 g, 0.001 mole) were combined. The reacinitiated at room temperature. After heating at 60° C. for 3 hours and heating at 80° C. for an additional 3 hours, the reaction was discontinued. Distillation gave 6.65 g (78 percent yield) of allyl benzoate which was identified by nuclear magnetic resonance spectroscopy.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04612386 |
|---|
| 出典データセット | uspto-grants-1986_09 |
|---|
| ORD ID | ord-39ac0fe3490b4b4ca1802b534a76f6ac |
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| 出典メモ | uspto-grants-1986_09 |
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