化工社化工社 化学情報印刷レポート · 研究参考用
1-Dodecanethiol → 3-(Dodecylsulfanyl)butanal
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-Dodecanethiol | HCID 8195 | — |
| 反応物 | Crotonaldehyde | HCID 447466 | — |
| 溶媒 | Triethylamine | HCID 8471 | — |
| 生成物 | 3-(Dodecylsulfanyl)butanal | HCID 13005022 | — |
反応手順
14.02 Grams of crotonaldehyde (0.20 mole) is added dropwise over a 40-minute period at 60° to 65° C. to a solution of 41.2 grams of n-dodecyl mercaptan (0.20 moles) and 0.66 grams of triethylamine after which heating and stirring are continued at 85° C. for 1.5 hours. Analysis of the reaction mixture indicates that the reaction is then substantially complete. The product is isolated as a light yellow liquid by stripping off the volatiles.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04612341 |
| 出典データセット | uspto-grants-1986_09 |
| ORD ID | ord-fbab261c40194fdd8da010af0aa35152 |
| 出典メモ | uspto-grants-1986_09 |