化工社化工社 化学情報印刷レポート · 研究参考用
Ammonia → 1-Amino-1-[4-methylpiperazino]-2-nitroethene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Ammonia | HCID 222 | — |
| 反応物 | 1-Methylpiperazine | HCID 53167 | — |
| 反応物 | 1,1-Bis(methylthio)-2-nitroethylene | HCID 83623 | — |
| 溶媒 | 1,1,1,2-Tetrachloroethane | HCID 12418 | — |
| 生成物 | 1-Amino-1-[4-methylpiperazino]-2-nitroethene | HCID 70350030 | — |
反応手順
An amount of 16.5 g of 1,1-bis-(methylthio)-2-nitroethene is dissolved at high temperature in 100 ml of tetrachloroethane, equimolar amounts of methyl-piperazine are added, the mixture is refluxed over 2 hours; the mass is cooled and anhydrous gaseous ammonia is added to it up to saturation.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04613602 |
| 出典データセット | uspto-grants-1986_09 |
| ORD ID | ord-67ce7d1c8b6e4df0965b3debb666c260 |
| 出典メモ | uspto-grants-1986_09 |