Sodium Methoxide → 2-Cyclopropyl-4-methoxy-6-(trichloromethyl)-1,3,5-triazine

HRID 652226ノート

反応式

HRID 652226 の反応式
[CH:1]1([C:4]2[N:9]=[C:8](C(Cl)(Cl)Cl)[N:7]=[C:6]([C:14]([Cl:17])([Cl:16])[Cl:15])[N:5]=2)[CH2:3][CH2:2]1.[CH3:18][O-:19].[Na+]>CO>[CH:1]1([C:4]2[N:9]=[C:8]([O:19][CH3:18])[N:7]=[C:6]([C:14]([Cl:17])([Cl:16])[Cl:15])[N:5]=2)[CH2:3][CH2:2]1

参加物

4

反応物 2

HCID 10942334Sodium MethoxideHCID 201996132-Cyclopropyl-4,6-bis-trichloromethyl-1,3,5-triazine

生成物 1

HCID 201996182-Cyclopropyl-4-methoxy-6-(trichloromethyl)-1,3,5-triazine

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

To a solution of 48 g of 2-cyclopropyl-4,6-bis-(trichloromethyl)-1,3,5-triazine in 200 ml of MeOH are added, with stirring, 4.9 g of sodium methylate, and the mixture is stirred for 1 hour at room temperature; it is then filtered and the filtrate is evaporated to dryness. The yield is 28.5 g of the title compound as a light-red oil, which solidifies after some time, m.p. 49°-51° C.

後処理

  1. filtrationit is then filtered
  2. customthe filtrate is evaporated to dryness

出典と根拠

ORDレコード
ord-16fb1c70e63e4e61be89e234bb424404
出典データセット
uspto-grants-1987_06
特許番号
US04670559

反応ノート

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