Chlorosuccinimide → HCID 20195427、化合物

HRID 653066ノート

反応式

HRID 653066 の反応式
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([S:8][CH2:9][C:10]#[N:11])=[CH:4][CH:3]=1.[Cl:12]N1C(=O)CCC1=O>C(Cl)(Cl)(Cl)Cl>[Cl:12][CH:9]([S:8][C:5]1[CH:4]=[CH:3][C:2]([Cl:1])=[CH:7][CH:6]=1)[C:10]#[N:11]

参加物

4

反応物 2

HCID 31398ChlorosuccinimideHCID 2778374[(4-Chlorophenyl)sulfanyl]acetonitrile

生成物 1

HCID 20195427HCID 20195427、化合物収率 10.6%

試薬・触媒・溶媒 1

HCID 5943Carbon Tetrachloride溶媒

実験手順

Into a 500 ml four-necked round bottom flask equipped with a stirrer, a thermometer, and a condenser, are placed 300 ml of carbon tetrachloride and 55 g (0.3 mole) of p-chlorophenylthioacetonitrile. To this mixture is added 40 g (0.3 mole) of N-chlorosuccinimide in small portions. The reaction mixture is stirred at room temperature overnight. The white solid which forms is filtered and the filtrate is concentrated under vacuum to give 6.95 g of desired product.

後処理

  1. customInto a 500 ml four-necked round bottom flask equipped with a stirrer
  2. filtrationThe white solid which forms is filtered
  3. concentrationthe filtrate is concentrated under vacuum

出典と根拠

ORDレコード
ord-88ec04252fff4f2d815425ea01651d54
出典データセット
uspto-grants-1987_06
特許番号
US04675316

反応ノート

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