Sulfuryl chloride → HCID 13382702、化合物

HRID 653070ノート

反応式

HRID 653070 の反応式
[C:1]1([S:7][CH2:8][CH2:9][CH2:10][C:11]#[N:12])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.S(Cl)([Cl:16])(=O)=O>C(Cl)Cl>[Cl:16][CH:8]([S:7][C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)[CH2:9][CH2:10][C:11]#[N:12]

参加物

4

反応物 2

HCID 24648Sulfuryl chlorideHCID 2715014-phenylsulfanylbutanenitrile

生成物 1

HCID 13382702HCID 13382702、化合物収率 102.9%

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

To a solution of 50 g (0.28 mole) of 4-phenylthiobutyronitrile in 200 ml of methylene chloride is added 40.5 g (0.3 mole) of sulfuryl chloride dropwise during a period of six hours. Stirring is continued overnight. Solvent and excess sulfuryl chloride is then evaporated under vacuum to give 61 g of a crude product. This material is used in the next experiment without further purification.

後処理

  1. customSolvent and excess sulfuryl chloride is then evaporated under vacuum

出典と根拠

ORDレコード
ord-c47a004dd6284f2babbf9e21b936bd50
出典データセット
uspto-grants-1987_06
特許番号
US04675316

反応ノート

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