3-Methyl-4-penten-1-ol → 3-Methyl-4-pentenyl 2-methylisocrotonate

HRID 65319

反応式

HRID 65319 の反応式
[C:1]([O:7][CH3:8])(=[O:6])/[C:2](=[CH:4]\[CH3:5])/[CH3:3].[CH3:9][CH:10]([CH:14]=C)[CH2:11][CH2:12]O.C([O-])(=O)CCCCCCCCCCC.C([Sn+2]CCCCCCCC)CCCCCCC.C([O-])(=O)CCCCCCCCCCC>C1(C)C=CC=CC=1>[C:1]([O:7][CH2:8][CH2:9][CH:10]([CH3:14])[CH:11]=[CH2:12])(=[O:6])/[C:2](=[CH:4]\[CH3:5])/[CH3:3]

参加物

5

反応物 3

HCID 1235253-Methyl-4-penten-1-olHCID 5356352Methyl (2Z)-2-methyl-2-butenoateHCID 22292224Dioctyltin laurate

生成物 1

HCID 162054563-Methyl-4-pentenyl 2-methylisocrotonate

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

実験手順

A mixture of 22.8 g. of methyl angelate, 10.0 g. of 3-methyl-4-pentenol, 100 ml. of toluene and 0.9 g. of dioctyltin laurate was reacted under the same conditions as in Example 1. The resulting mixture was subjected to single distillation to give 16.91 g. of a distillate boiling at 109° C. (21 mmHg). The distillate was further subjected to rectification to give 12.54 g. of a distillate boiling at 109° C. (21 mmHg). Analysis of the compound by gaschromatography done under the same conditions as in Example 12 indicated a purity of 99.653% in terms of the area ratio. Refractive index was 1.443.

後処理

  1. additionA mixture of 22.8 g
  2. distillationThe resulting mixture was subjected to single distillation
  3. customto give 16.91 g
  4. customto give 12.54 g

出典と根拠

ORDレコード
ord-2803290f8bd24e6097437ba0628ef4bc
出典データセット
uspto-grants-1986_09
特許番号
US04613680

関連ノート

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