Toluene → Dimethylammonium 5-(2-Chloro-4-trifluoromethylphenoxy)-2-nitrobenzoate

HRID 65332

反応式

HRID 65332 の反応式
[Cl:1][C:2]1[CH:20]=[C:19]([C:21]([F:24])([F:23])[F:22])[CH:18]=[CH:17][C:3]=1[O:4][C:5]1[CH:6]=[CH:7][C:8]([N+:14]([O-:16])=[O:15])=[C:9]([CH:13]=1)[C:10]([OH:12])=[O:11].[C:25]1(C)C=CC=CC=1>>[Cl:1][C:2]1[CH:20]=[C:19]([C:21]([F:22])([F:23])[F:24])[CH:18]=[CH:17][C:3]=1[O:4][C:5]1[CH:6]=[CH:7][C:8]([N+:14]([O-:16])=[O:15])=[C:9]([CH:13]=1)[C:10]([O-:12])=[O:11].[CH3:25][NH2+:14][CH3:8]

参加物

3

反応物 2

HCID 1140TolueneHCID 44073Acifluorfen

生成物 1

HCID 21280075Dimethylammonium 5-(2-Chloro-4-trifluoromethylphenoxy)-2-nitrobenzoate

実験手順

5-(2-Chloro-4-trifluoromethylphenoxy)-2-nitrobenzoic acid (2.0 g) is dissolved in toluene and an excess of anhydrous dimethylamine is bubbled into the reaction mixture, the solvent removed in vacuo and the residue triturated with cold diethyl ether to give 1.1 g of product.

後処理

  1. customan excess of anhydrous dimethylamine is bubbled into the reaction mixture
  2. customthe solvent removed in vacuo
  3. customthe residue triturated with cold diethyl ether

出典と根拠

ORDレコード
ord-27c9993c0cab40a29c432342e69b7bed
出典データセット
uspto-grants-1986_09
特許番号
US04613360

関連ノート

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