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Ethyl Acetate → 1-(4-Aminophenyl)-3-n-butyl-3-azabicyclo[3.1.1]heptane-2,4-dione
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Ethyl Acetate | HCID 8857 | — |
| 反応物 | 3-n-Butyl-1-(4-nitrophenyl)-3-azabicyclo[3.1.1]heptane-2,4-dione | HCID 20027825 | — |
| 触媒 | Palladium | HCID 23938 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | 1-(4-Aminophenyl)-3-n-butyl-3-azabicyclo[3.1.1]heptane-2,4-dione | HCID 20027835 | — |
反応手順
In a manner analogous to that described in Example 1, 2.08 g of 3-n-butyl-1-(4-nitrophenyl)-3-azabicyclo[3.1.1]heptane-2,4-dione in 60 ml of ethanol are hydrogenated in the presence of 0.15 g of palladium-on-carbon and worked up. Melting point 178°-179° (from ethyl acetate).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04677129 |
| 出典データセット | uspto-grants-1987_06 |
| ORD ID | ord-f42a7228885d4602b39d28f643c4ef82 |
| 出典メモ | uspto-grants-1987_06 |