1,4-Dichloro-2-butyne → Trichloro(1,4-dichlorobut-2-en-2-yl)silane

HRID 653539ノート

反応式

HRID 653539 の反応式
[Cl:1][CH2:2][C:3]#[C:4][CH2:5][Cl:6].[Cl:7][SiH:8]([Cl:10])[Cl:9]>C(O)(C)C>[Cl:1][CH2:2][C:3]([Si:8]([Cl:10])([Cl:9])[Cl:7])=[CH:4][CH2:5][Cl:6]

参加物

4

反応物 2

HCID 131821,4-Dichloro-2-butyneHCID 24811Trichlorosilane

生成物 1

HCID 53421800Trichloro(1,4-dichlorobut-2-en-2-yl)silane収率 94%

試薬・触媒・溶媒 1

HCID 3776Isopropanol触媒

実験手順

To a mixture of 15 ml (0.153 mol) of 1,4-dichloro-2-butyne and 13.6 ml (0.16 mol) of trichlorosilane (boiling point: 31°-32° C.) was added 0.15 ml (10 mmol) of an isopropyl alcohol solution of H2PtCl6.6H2O (0.05 g/ml), followed by heating for 8 hours. Thereafter, the mixture was directly distilled to obtain 37 g of 1,4-dichloro-2-(trichloro)silyl-2-butene. Yield: 94%. Boiling point: 70° C./1 mmHg.

後処理

  1. temperatureby heating for 8 hours
  2. distillationThereafter, the mixture was directly distilled

出典と根拠

ORDレコード
ord-8751323158664cecab651c90daada4da
出典データセット
uspto-grants-1987_06
特許番号
US04677216

反応ノート

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