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3-Chloro-2-methyl-1-propene → Et3SiCH2CHMeCH2Cl
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 3-Chloro-2-methyl-1-propene | HCID 11241 | — |
| 反応物 | Triethylsilane | HCID 12052 | — |
| 反応物 | Trichlorosilane | HCID 24811 | — |
| 生成物 | Et3SiCH2CHMeCH2Cl | HCID 13765477 | 82.5% |
反応手順
In a 100 ml apparatus, there were combined 11.6 g (0.1 mol) of Et3SiH, 13.6 g (0.1 mol) of Cl3SiH, and 9.1 g of methallyl chloride, followed by addition of 0.05 ml Pt catalyst solution at 21° C. There was a rapid and exothermic reaction to 61° C. in 2 min. Reaction appeared to have stopped and was heated to reflux over 4 hrs. when VPC showed complete reaction. Vacuum distillation yielded 17.03 g (82.5%) of Et3SiCH2CHMeCH2Cl, indicating that Cl3SiH is an effective promoter for the reaction of Et3SiH with methallyl chloride.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04614812 |
| 出典データセット | uspto-grants-1986_09 |
| ORD ID | ord-f39d2b08875149bdb1d257b2845989f0 |
| 出典メモ | uspto-grants-1986_09 |