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3-Chloro-2-methyl-1-propene → Chloro(3-chloro-2-methylpropyl)dimethylsilane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 3-Chloro-2-methyl-1-propene | HCID 11241 | — |
| 反応物 | Triethylsilane | HCID 12052 | — |
| 反応物 | Chlorodimethylsilane | HCID 66108 | — |
| 生成物 | Chloro(3-chloro-2-methylpropyl)dimethylsilane | HCID 86665 | 81.1% |
| 生成物 | Et3SiCH2CHMeCH2Cl | HCID 13765477 | 3.6% |
反応手順
In a 100 ml apparatus, there were combined 7.1 g (0.075 mol) of Me2SiHCl, 8.7 g (0.075 mol) of Et3SiH, and 6.8 g (0.075 mol) of methallyl chloride. Pt catalyst solution (0.01 ml) was added at 32° C., causing an exothermic reaction to 94° C. in 4 min. Distillation of the complete reaction yielded 81.1% Me2SiClCH2CHMeCH2Cl and 3.6% Et3SiCH2CHMeCH2Cl. Et3SiH does promote slightly the reaction of Me2SiHCl with methallyl chloride.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04614812 |
| 出典データセット | uspto-grants-1986_09 |
| ORD ID | ord-2f5e7452a4894c848e123c28912fd0ca |
| 出典メモ | uspto-grants-1986_09 |