関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | 3-Chloro-2-methyl-1-propene | HCID 11241 | — |
| 反応物 | Chlorodimethylsilane | HCID 66108 | — |
| 生成物 | Chloro(3-chloro-2-methylpropyl)dimethylsilane | HCID 86665 | 83.4% |
反応手順
In a 100 ml apparatus, there were combined 14.2 g (0.15 mol) of Me2SiHCl and 13.6 g (0.15 mol) of methallyl chloride, followed by 0.05 ml Pt catalyst solution at 21° C. Gentle heating caused a smooth exothermic reaction to 90° C. in 16 in. Reaction was heated at 80° C. until completed (50 min). Vacuum distillation yielded 23.14 g (83.4%) of Me2SiClCH2CHMeCH2Cl.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04614812 |
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| 出典データセット | uspto-grants-1986_09 |
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| ORD ID | ord-358f42d57f2345dc8b028c1b7c81a5ce |
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| 出典メモ | uspto-grants-1986_09 |
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