化工社化工社 化学情報印刷レポート · 研究参考用
Allyl chloride → Silane, chloro(3-chloropropyl)dimethyl-
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Allyl chloride | HCID 7850 | — |
| 反応物 | Triethylsilane | HCID 12052 | — |
| 反応物 | Chlorodimethylsilane | HCID 66108 | — |
| 生成物 | Silane, chloro(3-chloropropyl)dimethyl- | HCID 82765 | 42.5% |
| 生成物 | (3-Chloropropyl)(triethyl)silane | HCID 12566784 | 4.8% |
反応手順
In a 100 ml apparatus, there were combined 7.1 g (0.075 mol) of Me2SiHCl, 8.7 g (0.075 mol) of Et3SiH and 5.7 g (0.075 mol) of allyl chloride. Pt catalyst solution was added (0.05 ml) at 34° C. Gentle heating caused a smooth exothermic reaction to 92° over 36 min. Vacuum distillation yielded 42.5% of Me2SiClCH2CH2CH2Cl and 4.8% of Et3SiCH2CH2CH2Cl. This example shows that Et3SiH at the equimolar level is an effective promoter for the reaction between Me2SiHCl and allyl chloride.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04614812 |
| 出典データセット | uspto-grants-1986_09 |
| ORD ID | ord-ea010ac8c17a469998fda743e4cb84e6 |
| 出典メモ | uspto-grants-1986_09 |