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Allyl chloride → Trichloro(3-chloropropyl)silane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Allyl chloride | HCID 7850 | — |
| 反応物 | Trichlorosilane | HCID 24811 | — |
| 反応物 | Chlorodimethylsilane | HCID 66108 | — |
| 生成物 | Trichloro(3-chloropropyl)silane | HCID 75693 | 60.4% |
| 生成物 | Silane, chloro(3-chloropropyl)dimethyl- | HCID 82765 | 8.6% |
反応手順
In a 100 ml apparatus, there were combined 7.1 g (0.075 mol) of Me2SiHCl, 10.2 g (0.075 mol) of Cl3SiH, and 5.7 g (0.075 mol) of allyl chloride. Pt catalyst solution (0.01 ml) was added at 33° C., causing an exothermic reaction to 47° C. in 7 min. VPC analysis 14 min. later showed a complete reaction. Vacuum distillation yielded 60.4% Cl3SiCH2CH2CH2Cl and 8.6% Me2SiClCH2CH2CH2Cl. This example shows that Me2SiHCl is an effective promoter for the reaction of Cl3SiH with allyl chloride at the equimolar level.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04614812 |
| 出典データセット | uspto-grants-1986_09 |
| ORD ID | ord-06de58a16da846138f2f5fd1e934bfcb |
| 出典メモ | uspto-grants-1986_09 |