関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Phenylacetylene | HCID 10821 | — |
| 反応物 | 1-Bromo-2-nitrobenzene | HCID 11341 | — |
| 触媒 | Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI) | HCID 24350 | — |
| 生成物 | Stk331085 | HCID 800027 | 84% |
反応手順
Example 1 was repeated except phenylacetylene ##STR9## was employed as the sole alkyne (25 mmols); the amount of CuI was increased to 0.25 mmol; and the reaction temperature was increased to 56° C. After 24 hours, the bromonitrobenzene was totally converted, giving an 84% yield of phenyl-3-nitrophenylacetylene ##STR10## Example 16 shows that it is not predictable (when Ex. 16 is compared with Exs. 13-15) which charge stocks will react with which halogenated arenes.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04128588 |
|---|
| 出典データセット | uspto-grants-1978_12 |
|---|
| ORD ID | ord-3b65ac9c63ba47d7a4d85e4fa6c0c919 |
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| 出典メモ | uspto-grants-1978_12 |
|---|
