関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | N-bromobutanimide | HCID 67184 | — |
| 反応物 | Pyrene, 1-(1,1-dimethylethyl)- | HCID 187956 | — |
| 溶媒 | 1,2-Dimethoxyethane | HCID 8071 | — |
| 生成物 | Bromo-tert-butylpyrene | HCID 86639773 | 90% |
反応手順
Next, 25.0 g (0.10 mol) of tert-butylpyrene and 250 ml of DME (1,2-dimethoxyethane) were charged in a reaction vessel, and the mixture was cooled to 0° C. Next, NBS was added in an amount of 4 equivalents relative to tert-butylpyrene, and the resulting mixture was stirred overnight at room temperature, filtered, and recrystallized to produce 29.5 g of bromo-tert-butylpyrene crystals in a yield of 90%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US08071993B2 |
|---|
| 出典データセット | uspto-grants-2011_12 |
|---|
| ORD ID | ord-5f32d15fadfa4e929daf62d905b40864 |
|---|
| 出典メモ | uspto-grants-2011_12 |
|---|
