関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Nitrogen oxide (N2O4) | HCID 25352 | — |
| 反応物 | 3-Phenylnaphtho-[1,2-b]furan-5-carboxylic acid | HCID 15571609 | — |
| 溶媒 | Chloroform | HCID 6212 | — |
| 生成物 | 2-Nitro-3-phenylnaphtho-[1,2-b]furan-5-carboxylic acid | HCID 15571606 | — |
反応手順
The product of Step A is dissolved partially in 125 ml. of hot chloroform, and 1 g. of dinitrogen tetraoxide is added. The mixture is stirred at 20° C. for about 1 day. The mixture is evaporated to provide a residue which is triturated with isopropyl alcohol. The residue is separated by filtration and recrystallized from acetic acid to provide light yellow crystals of 2-nitro-3-phenylnaphtho-[1,2-b]furan-5-carboxylic acid, m.p. 286°-288° c. (dec.).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04128659 |
|---|
| 出典データセット | uspto-grants-1978_12 |
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| ORD ID | ord-6729330bbb84464e967b2f906950945c |
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| 出典メモ | uspto-grants-1978_12 |
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