化工社化工社 化学情報印刷レポート · 研究参考用
Furfuryl Alcohol → 5-[(Methylamino)methyl]-2-furanmethanol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Furfuryl Alcohol | HCID 7361 | — |
| 反応物 | Sodium Carbonate | HCID 10340 | — |
| 反応物 | Methylamine hydrochloride | HCID 6364545 | — |
| 溶媒 | Formaldehyde | HCID 712 | — |
| 生成物 | 5-[(Methylamino)methyl]-2-furanmethanol | HCID 14671747 | — |
反応手順
A mixture of 2-furanmethanol (49 g), methylamine hydrochloride (51.5 g) and 36% formaldehyde solution (50 ml) was stirred at 0°-3° for 3 hr and allowed to stand for 16 hr. Excess sodium carbonate was added and the slurry extracted with ethyl acetate. After removal of solvent the residue was distilled to give 5-(methylamino)methyl-2-furanmethanol (36.2 g) b.p. 111°-113° (0.2 mm).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04128658 |
| 出典データセット | uspto-grants-1978_12 |
| ORD ID | ord-d367991a172444eabb875f75fdc2f518 |
| 出典メモ | uspto-grants-1978_12 |