関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Sodium Fluoride | HCID 5235 | — |
| 反応物 | CF3CF2CF2Ocf2CF2CF2ococf(CF3)ocf2CF2CF3 | HCID 131723953 | — |
| 生成物 | 2,2,3,3-tetrafluoro-3-(1,1,2,2,3,3,3-heptafluoropropoxy)propanoyl Fluoride | HCID 11739051 | 57% |
反応手順
CF3CF2CF2OCF2CF2CF2OCOCF(CF3)OCF2CF2CF3 (0.8 g) obtained in Example 42 was charged into a flask together with a NaF powder (0.01 g) and heated at 120° C. for 10 hours in an oil bath with vigorous stirring. At an upper portion of the flask, a reflux condenser adjusted to a temperature of 20° C. was installed. After cooling, a liquid sample (0.7 g) was recovered. By GC-MS, it was confirmed that CF3CF(OCF2CF2CF3)COF and the above-identified compound were the main products. The yield was 57.0%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US07083705B2 |
|---|
| 出典データセット | uspto-grants-2006_08 |
|---|
| ORD ID | ord-6ba226ea566049a98b1b22bf00db0771 |
|---|
| 出典メモ | uspto-grants-2006_08 |
|---|
