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Hexane → p-Divinylbenzene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Hexane | HCID 8058 | — |
| 反応物 | Chlorodimethylsilane | HCID 66108 | — |
| 反応物 | (Styrylethyl)-trichlorosilane | HCID 57297925 | — |
| 触媒 | Platinum | HCID 23939 | — |
| 生成物 | p-Divinylbenzene | HCID 66041 | — |
反応手順
(Styrylethyl)-trichlorosilane is first synthesized by a platinum-catalyzed mono-hydrosilylation of p-DVB with chlorodimethylsilane in hexane. Kim, I-J.; Faust, R. Polym. Prepr., (Am. Chem. Soc. Div. Polym. Chem) 2000, 41(2), 1309. A styryl-POSS macromer is then prepared by corner capping reaction of incompletely condensed trisilanol (c-C5H9)7Si7O9(OH)3 with (styrylethyl)-trichlorosilane, according to the procedure reported in Haddad, T. S.; Lichtenhan, J. D. Macromolecules 1996, 29, 7302.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08075906B2 |
| 出典データセット | uspto-grants-2011_12 |
| ORD ID | ord-8f775f514068446bbda78c8538229c68 |
| 出典メモ | uspto-grants-2011_12 |