(3-Methoxy-4-methylphenyl)methanol → 3-Methoxy-4-methylbenzaldehyde
反応式
[CH3:1][O:2][C:3]1[CH:4]=[C:5]([CH2:10][OH:11])[CH:6]=[CH:7][C:8]=1[CH3:9]>[O-2].[Mn+2].ClCCl>[CH3:1][O:2][C:3]1[C:8]([CH3:9])=[CH:7][CH:6]=[C:5]([CH:4]=1)[CH:10]=[O:11]参加物
4
実験手順
At ambient temperature, 36.35 g (238.8 mmol) of (3-methoxy-4-methylphenyl)-methanol and 207.6 g (2.4 moles/10 eq.) of manganese oxide are mixed into 730 mL of dichloromethane. Stirring is carried out at ambient temperature overnight, followed by filtration over Celite and rinsing with dichloromethane. After concentration of the combined filtrates, the desired product is obtained.
後処理
- filtrationfollowed by filtration over Celite
- washrinsing with dichloromethane
出典と根拠
- ORDレコード
- ord-96a21904e825421cb070c88fd0d19996
- 出典データセット
- uspto-grants-2011_12
- 特許番号
- US08076325B2
反応ノート
読み込み中…